SPRAY large baking sheet with cooking spray. Microwave sugar and corn syrup in large glass microwaveable bowl on HIGH 5 min., stirring after 3 min. Stir in pecans. Microwave 3 to 5 min. or until golden brown.
ADD butter, vanilla and hot pepper sauce; stir until butter is melted. Microwave 1 min. Stir in baking soda. (Mixture will foam.) Spread onto prepared baking sheet. Cool completely. Break into pieces.